PSG, the French Cup winners, face Ligue 1 champions Lille in Sunday's Champions Trophy being played this year in Tel Aviv.
Ramos, 35, signed a two-year contract with PSG earlier this month after a storied career with Real Madrid where he won the Champions League four times.
He is also a World Cup winner and a two-time champion of Europe with Spain.
Ramos currently holds the record as the most capped player in the history of the Spanish national team and is his country's eighth-highest all-time goalscorer.
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