Goals from Victor Osimhen, Amir Rrahmani, Kalidou Koulibaly, and Hirving Lozano earned Spalletti's side an impressive win at the Dacia Arena which gives them a perfect 12 points from four games, two points ahead of Inter Milan and AC Milan, who sit second and third respectively.
Roma are a further point back alongside Fiorentina as Napoli remain the only team to win all of their matches so far this term in Italy's top flight.
Udinese meanwhile sit seventh, level on seven points with Lazio, Atalanta, and Bologna.
Osimhen followed up on his dramatic brace in Thursday's 2-2 Europa League draw at Leicester City by opening the scoring in the 24th minute with his first Serie A goal of the campaign, poking home from near the goalline after Lorenzo Insigne had deftly lobbed Udinese goalkeeper Marco Silvestri.
Fabian Ruiz then struck the post six minutes later and was key to the goal which put Napoli two ahead.
Receiving the ball from Insigne at a free-kick, Ruiz floated a delicate pass over the top of the Udinese defence for Koulibaly, who pushed the ball across goal for Rrahmani to nod home.
Koulibaly scored the late winner against Juventus last time out and put Napoli three up six minutes after the break with a missile of a shot from the excellent Ruiz's layoff.
From then on it was all Napoli and Lozano put the cherry on the cake in the 84th minute with a lovely finish following an exchange of passes with Mario Rui.
Oladimeji Balogun is a graduate of the University of Ilorin where he studied Microbiology, he is a w...
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